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hydrogen-benchmark-PRX

This is the main directory for the hydrogen chain benchmark data. Please contact [email protected] or [email protected] (alternatively [email protected]) for questions

Paper: Phys. Rev. X 7, 031059 (2017)

Title: Towards the Solution of the Many-Electron Problem in Real Materials: Equation of State of the Hydrogen Chain with State-of-the-Art Many-Body Methods

Authors: Mario Motta, David M. Ceperley, Garnet Kin-Lic Chan, John A. Gomez, Emanuel Gull, Sheng Guo, Carlos A. Jiménez-Hoyos, Tran Nguyen Lan, Jia Li, Fengjie Ma, Andrew J. Millis, Nikolay V. Prokof'ev, Ushnish Ray, Gustavo E. Scuseria, Sandro Sorella, Edwin M. Stoudenmire, Qiming Sun, Igor S. Tupitsyn, Steven R. White, Dominika Zgid, and Shiwei Zhang (Simons Collaboration on the Many-Electron Problem)

DOI: https://doi.org/10.1103/PhysRevX.7.031059

This work is licensed under a Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/).

Data are in the directories N_number_OBC, N_number_PBC, Thermodynamic-Limit with

OBC open boundary conditions PBC periodic boundary conditions number number of particles (number=10,18,...,102)

Inside these directories are data from different methods, named after the technique and basis set

technique_basis-b (Examples: DMRG_basis-DZ, AFQMC_basis-CBS, SBDMRG_basis-SBDZ)

Technique List:

AFQMC: auxiliary-field quantum Monte Carlo

BDMC: bold diagrammatic Monte Carlo

DMET: density-matrix embedding theory

DMRG: density-matrix renormalization group with a quantum chemistry basis

FCI: full configuration interaction

GF2: self-consistent second-order Green's function

LRDMC: lattice-regularized diffusion Monte Carlo

MRCI: multireference configuration interaction without Davidson correction

MRCI+Q: multireference configuration interaction with Davidson correction

MRCI+Q+F12: multireference configuration interaction with Davidson and F12 correction

PC-NEVPT2: strongly contracted N-electron valence state second-order perturbation theory

SC-NEVPT2: partially contracted N-electron valence state second-order perturbation theory

RHF: restricted Hartree-Fock

RCCSD: restricted coupled-cluster with full treatment of singles and doubles

RCCSD(T): restricted coupled-cluster with full treatment of singles and doubles and perturbative treatment of triples

SC-GW: fully self-consistent GW

SBDMRG: specialized DMRG with sliced basis sets

SEET: self-energy embedding theory

UHF: unrestricted Hartree-Fock

UCCSD: unrestricted coupled-cluster with full treatment of singles and doubles

UCCSD(T): unrestricted coupled-cluster with full treatment of singles and doubles and perturbative treatment of triples

UGF2: spin-unrestricted self-consistent second-order Green's function

VMC: variational Monte Carlo [52,53]

Basis List:

STO: STO-6G

DZ : cc-pVDZ

TZ : cc-pVTZ

QZ : cc-pVQZ

5Z : cc-pV5Z

SBSTO: sliced-basis STO

SBDZ: sliced-basis cc-pVDZ

SBTZ: sliced-basis cc-pVTZ

CBS: complete basis set limit

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