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"Spatiotemporal Variability of Gas Transfer Velocity in a Tropical High-Elevation Stream Using Two Independent Methods"

Authors: Keridwen M. Whitmore*, Nehemiah Stewart*, Andrea Encalada, Esteban Suarez, Diego Riveros-Iregui

*These authors contributed equally to this work.

This repository serves to host data and analyses used in the research supporting the work in "Spatiotemporal Variability of Gas Transfer Velocity in a Tropical High-Elevation Stream Using Two Independent Methods", submitted to Ecosphere.

Purpose

To provide access to the data and make analyses reproducible for others. All figures presented in the paper were created using R statistical software. Scripts and data files for creating our figures are provided within this repository. If you have Rstudio installed on your computer, you should be able to 'fork' this repository and run it on your local computer to reproduce the anlayses in this paper without any alterations.

Instructions to run this code

This code was written and run with R version 3.6.2 and R Studio version 1.2.5001. You can download this repository to your local computer and open the project file Whitmore_et_al_2021.Rproj. We use the here package to ensure that the code will run on any computer without having to change any file paths.

Guide to Folders

data

  • File: "KatStn1_df.csv"

*these data are used to create figures 3 & 4 *

Column Name Description
DateTime Date and Time of collection
Flux_1 Carbon dioxide flux, unit no 1 (umole per meter squared per sec)
airTemp_c Air Temperature (c)
tempC_421 Temperature (c) at station 1
stn1_Q Discharge at station 1 (m3s-1)
air_pressure_kPa Air pressure (kPa)
V1_adjusted partial pressure of CO2 adjusted for temperature and pressure at Station 1 (ppm)
CO2_air_ppm estimated partial pressure of atmospheric CO2 (ppm)
air_pressure_atm Barometric pressure (atm)
VaporPressure_atm Vapor pressure (atm)
TotalAir_atm air pressure as dry air (atm)
Total_air_MolperL air pressure as dry air (moles per Liter)
CO2_air_MolesPerLiter CO2 concentration in air (moles per Liter)
CO2_air_gCO2asCPerLiter CO2 concentration in air (grams of CO2 as C per Liter)
WaterTemp_K water temperature (kelvin)
KH_mol.L.atm Henry's constant (moles per Liter per atm)
CO2_water_gCO2asCPerLiter CO2 concentration in the water (grams of CO2 as C per Liter)
deltaCO2_gCO2asCperM3 difference between CO2 concentration in the air and dissolved CO2 concentration (grams of CO2 as C per Liter)
Flux_gCO2asCperM2perDay Carbon dioxide flux, unit no 1 (grams per meters squared per day)
k_m.d gas transfer velocity (meters squared per sec)
Sc Schmidt number
K600.effective measured k600 at station 1 (meters squared per sec)
kkin kinematic K600 label
K600.eq1 kinematic k600 at station 1 (meters squared per sec)

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  • File: "KatStn4_df.csv"

*these data are used to create supplementary figure 3 *

Column Name Description
DateTime Date and Time of collection
Flux_2 Carbon dioxide flux, unit no 2 (umole per meter squared per sec)
airTemp_c Air Temperature (c)
tempC_421 Temperature (c) at station 1
stn1_Q Discharge at station 1 (m3s-1)
air_pressure_kPa Air pressure (kPa)
V4_adjusted partial pressure of CO2 adjusted for temperature and pressure at Station 4 (ppm)
CO2_air_ppm estimated partial pressure of atmospheric CO2 (ppm)
air_pressure_atm Barometric pressure (atm)
CO2_air_gCO2asCPerLiter CO2 concentration in air (grams of CO2 as C per Liter)
WaterTemp_K water temperature (kelvin)
KH_mol.L.atm Henry's constant (moles per Liter per atm)
CO2_water_gCO2asCPerLiter CO2 concentration in the water (grams of CO2 as C per Liter)
deltaCO2_gCO2asCperM3 difference between CO2 concentration in the air and dissolved CO2 concentration (grams of CO2 as C per Liter)
Flux_gCO2asCperM2perDay Carbon dioxide flux, unit no 2 (grams per meters squared per day)
k_m.d gas transfer velocity at station 4 (meters squared per sec)
Sc Schmidt number
K600.E.stn4 measured k600 at station 4 (meters squared per sec)

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  • File name: PrecipitationData.csv

*these data are used to create Supplimentary figure 1 *

Column Name Description
DateTime Date and Time of collection
ppt_mm precipitation accumulation at 15 min intervals [mm]
ppt24Tot 24-hour total precipitation [mm]
stn1_Q Discharge at station 1 (m3s-1)

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  • File: Synoptic_Kin600.csv

these data are used to create figures 5 & 6

Column Name Description
Date Date of collection
transect synoptic transect
dist.m distance from outlet (meters)
elev.m elevation (meters)
slope.unitless slope (unitless)
depth.m water depth (meters)
velocity.m.s velocity (meters per sec)
Discharge.m3.s discharge (cubic meters per sec)
K600.eq1 kinematic k600 (meters squared per sec)

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  • File: Synoptic_Kin600.csv

these data are used to create figures 5 & 6

Column Name Description
DOY Day of year of collection
slope.unitless slope (unitless)
depth.m water depth (meters)
velocity.m.s velocity (meters per sec)
dist.m.AVE distance from outlet (meters)
CO2_ppm dissolved CO2 concentration (ppm)
ave.time median time of collection during synoptic collection date
Synoptic_no synoptic location sampled
Flux_ave_umol_m3_s Average of 3 Flux measurments collected at sample location (umol per cubic meters per sec)
Flux_StdDev Standard deviation of 3 Flux measurments collected at sample location (umol per cubic meters per sec)
WaterTemp_c water temperature (celcius)
Q_m3perS Average discharge during sample period (cubic meter per sec)
air_pressure_kPa Air pressure (kPa)
Date Date of collection
K600.eq1 kinematic k600 (meter squared per sec)
air_pressure_atm Air pressure (atm)
VaporPressure_atm Vapor pressure (atm)
CO2_air_MolesPerLiter atmospheric CO2 (moles per liter)
CO2_air_gCO2asCPerLiter atmospheric CO2 (grams of CO2 as C per liter)
WaterTemp_K water temperature (kelvin)
KH_mol.L.atm Henry's constant (moles per Liter per atm)
CO2_water_gCO2asCPerLiter CO2 concentration in the water (grams of CO2 as C per liter)
deltaCO2_gCO2asCperM3 difference between CO2 concentration in the air and in the water (grams of CO2 as C per m^3)
Flux_gCO2asCperM2perDay Carbon dioxide flux, unit no 1 (grams of CO2 as C per meters squared per day)
k_m.d gas transfer velocity (meters squared per sec)
Sc Schmidt number
K600.effective measured k600 (meters squared per sec)

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scripts

File Name Type Description
Fig3.R R code figure 3
Fig4.R R code figure 4
Fig5.R R code figure 5
Fig6.R R code figure 6
SuppFig1.R R code supplementary figure 1
SuppFig2.R R code supplementary figure 2
SuppFig3.R R code supplementary figure 3

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Points of contact

Direct questions about the paper to Dr. Diego Riveros-Iregui: [email protected]

Direct questions about the code to Kriddie Whitmore: [email protected]>