diff --git a/browser/password_manager/android/brave_password_manager_android_util_unittest.cc b/browser/password_manager/android/brave_password_manager_android_util_unittest.cc
index 5322439432a0..f492ff6a6fe2 100644
--- a/browser/password_manager/android/brave_password_manager_android_util_unittest.cc
+++ b/browser/password_manager/android/brave_password_manager_android_util_unittest.cc
@@ -7,6 +7,7 @@
 #include "base/files/file_util.h"
 #include "base/test/scoped_feature_list.h"
 #include "base/test/test_file_util.h"
+#include "base/types/cxx23_to_underlying.h"
 #include "chrome/browser/password_manager/android/password_manager_android_util.h"
 #include "components/password_manager/core/browser/features/password_features.h"
 #include "components/password_manager/core/browser/password_manager_constants.h"
@@ -37,7 +38,7 @@ class BravePasswordManagerAndroidUtilTest : public testing::Test {
         0);
     pref_service_.registry()->RegisterIntegerPref(
         password_manager::prefs::kPasswordsUseUPMLocalAndSeparateStores,
-        static_cast<int>(kOff));
+        base::to_underlying(kOff));
     pref_service_.registry()->RegisterBooleanPref(
         password_manager::prefs::kCredentialsEnableService, false);
     pref_service_.registry()->RegisterBooleanPref(
@@ -90,7 +91,7 @@ TEST_F(BravePasswordManagerAndroidUtilTest,
 
   // This is a state of a local user that has just been migrated.
   pref_service()->SetInteger(kPasswordsUseUPMLocalAndSeparateStores,
-                             static_cast<int>(kOn));
+                             base::to_underlying(kOn));
   pref_service()->SetBoolean(
       password_manager::prefs::kUserAcknowledgedLocalPasswordsMigrationWarning,
       true);
@@ -119,9 +120,12 @@ TEST_F(BravePasswordManagerAndroidUtilTest,
 
   SetUsesSplitStoresAndUPMForLocal(pref_service(), login_db_directory());
 
-  // SetUsesSplitStoresAndUPMForLocal must not delete DB on Brave
+  // Pref should be kOff, as we want keep using profile store instead of the
+  // account store, so the paswords will be synced from Android to Desktop
   EXPECT_EQ(pref_service()->GetInteger(kPasswordsUseUPMLocalAndSeparateStores),
-            static_cast<int>(kOn));
+            base::to_underlying(kOff));
+
+  // SetUsesSplitStoresAndUPMForLocal must not delete DB on Brave
   EXPECT_TRUE(PathExists(profile_db_path));
   EXPECT_TRUE(PathExists(account_db_path));
   EXPECT_TRUE(PathExists(profile_db_journal_path));
diff --git a/chromium_src/chrome/browser/password_manager/android/password_manager_android_util.cc b/chromium_src/chrome/browser/password_manager/android/password_manager_android_util.cc
index 58ffe9936f53..76f989bff938 100644
--- a/chromium_src/chrome/browser/password_manager/android/password_manager_android_util.cc
+++ b/chromium_src/chrome/browser/password_manager/android/password_manager_android_util.cc
@@ -3,6 +3,9 @@
  * License, v. 2.0. If a copy of the MPL was not distributed with this file,
  * You can obtain one at https://mozilla.org/MPL/2.0/. */
 
+#include "components/password_manager/core/common/password_manager_pref_names.h"
+#include "components/prefs/pref_service.h"
+
 #define SetUsesSplitStoresAndUPMForLocal \
   SetUsesSplitStoresAndUPMForLocal_ChromiumImpl
 
@@ -12,11 +15,42 @@
 
 namespace password_manager_android_util {
 
+namespace {
+
+// On Android passwords can be saved into two stores: kAccountStore and
+// kProfileStore. Account store is not synced through Chromium sync and supposed
+// to store passwords at Google Account. Profile store is the store which saves
+// passwords at profile and passwords are synced as before. Decision which store
+// to use is made at PasswordSaveManagerImpl::GetPasswordStoreForSavingImpl.
+// Finally, `kPasswordsUseUPMLocalAndSeparateStores` pref is checked.
+// The stack:
+//        features_util::CanCreateAccountStore
+//        features_util::internal::CanAccountStorageBeEnabled
+//        features_util::internal::IsUserEligibleForAccountStorage
+//        features_util::GetDefaultPasswordStore
+//        PasswordFeatureManagerImpl::GetDefaultPasswordStore
+//        PasswordSaveManagerImpl::AccountStoreIsDefault
+//        PasswordSaveManagerImpl::GetPasswordStoreForSavingImpl
+// There are two ways to make passwords be saved at the profile store and be
+// synced:
+//   1) override PasswordSaveManagerImpl::AccountStoreIsDefault
+//   2) set `kPasswordsUseUPMLocalAndSeparateStores` pref to `kOff`
+// Choosing option 2.
+void ForcePasswordsProfileStore(PrefService* pref_service) {
+  pref_service->SetInteger(
+      password_manager::prefs::kPasswordsUseUPMLocalAndSeparateStores,
+      static_cast<int>(UseUpmLocalAndSeparateStoresState::kOff));
+}
+
+}  // namespace
+
 // Prevent deleting passwords local DB during migration.
 // Happens at SetUsesSplitStoresAndUPMForLocal =>
 //      MaybeDeactivateSplitStoresAndLocalUpm =>
 //      MaybeDeleteLoginDataFiles
 void SetUsesSplitStoresAndUPMForLocal(
     PrefService* pref_service,
-    const base::FilePath& login_db_directory) {}
+    const base::FilePath& login_db_directory) {
+  ForcePasswordsProfileStore(pref_service);
+}
 }  // namespace password_manager_android_util